March 20, 2004 notes
Working engines
We finally have a solid engine configuration!
The angle bar flameholders were causing combustion
instability at high thrust and melting things underneath them, so we focused on
using the heavy perforated metal plates as flameholders. A single plate retaining the cold pack with
the spark plug underneath it worked ok, but if we added a second one right
below the spark plug, we got much stronger and more even flameholding. We also started using the longest reach
spark plugs I could find NGK PLFR5A-11, which gives over an inch of reach to
get it past the 5.5 to 7 step transition.
This would light reliably if the pack was completely cold, but it still
had problems when we tried to light it a second time.
We had found in the past that the voodoo ritual of briefly opening
the valve very wide when it wasnt starting would allow it to start again, so
we pursued that and found that it did seem to be a reliable way of starting a
hot engine. John Carr, a local
combustion chemist that I had been corresponding with, had stopped by on Tuesday
to see if he could help, and he was able to offer us a logical explanation for
the behavior. When we had a run that
wouldnt start, you could smell formaldehyde, which is what methanol breaks
down to on a catalyst (along with hydrogen).
He also pointed out that at 100C and the molar fraction of methanol in
our mixture, there actually isnt all that much methanol completely
vaporized. Apparently, if the monolith
catalyst in the cold pack has gotten much of any heat soaked back into it then
it will start attacking the methanol as well as the peroxide, and if much of it
gets catalytically burned, then there isnt an ignitable O/F ratio by the spark
plug. A large slug of propellant will
cool the catalyst back down so it operates at the level we want it to.
We have now done over a dozen full thrust firings with this
procedure, with no problems. If the
engine is hot, it isnt even worth trying to start it at the normal warmup flow
rate, we just start it right off with a big slug of propellant to wash the heat
down, then drop it to the normal warmup level in the 12% - 20% throttle
range. We also found that it didnt
require a particularly strong spark, so we went all the way from the MSD10-Pro back
to the MSD small engine ignition controller with no problems. This saves a non-trival amount of mass, power,
space, and several thousand dollars.
With two thermocouple probes in the engine we have seen a
couple anomalies in the hot pack behavior, where sometimes both the upper and
lower sections of it stay hot for the entire run, and on other runs the top section
collapses down to about 250 C, while the bottom section stays at 1000 C. It doesnt seem to effect the engine, but it
implies that we have more catalyst than necessary, and I dont like the
distinction. The existing hot packs
have two layers of 500 grams of rings each in a 7 diameter, which is quite a
bit more than what we had in the 5.5 engines.
When we originally tried a single layer of 600 grams of rings in a 5.5
engine the rings on the bottom had too much pressure on them, resulting in many
of them collapsing and increasing the pressure drop. With the 7 ID chambers we should be able to have more rings in a
single layer both because of the increased area and because the pressure drop
is lower due to the greater chamber to throat contraction ratio.
We considered making a 600 gram layer, but many of our
catalysts seem to have a minimum critical depth regardless of the mass or flow,
so we bumped it up a little bit to 700 grams.
In the interest of avoiding an unwanted flameholder right above the
rings and to save some mass, we used a 10 mesh 316 screen on top to hold the
rings in place instead of a disk of perforated metal. This engine warmed up considerably faster than the older engines,
which is to be expected due to having less than half the mass in the hot pack
(700 g vs 1000 g of catalyst, only one heavy perf plate, and a screen instead
of a light perf plate). The temperature
profile was great, actually slightly hotter than normal. We then did a 15 gallon run with no
problems, but the side of the engine showed some uneven heating. When we did another long run there were
combustion oscillations. We cut the
engine apart and found that the 316 screen on top had melted / oxidized away and clumped onto the rings below it,
allowing the rings to get all out of shape and partially block some of the
flow. The fact that the engine ran
completely clear even with the rings not evenly distributed implies that we can
get by with even less, so our next build will probably only use 600 grams of
rings, and we will go back to using a medium weight perf plate as a top retainer
for the rings.
We also did a test with opening up the main propellant flow
a bit earlier, and found that 600 C at the bottom of the engine isnt enough, but
800 C is. While we could probably get
by with a fixed warmup profile on the vehicle, I decided it is worthwhile to go
ahead and add thermocouple amplifiers on the vehicle so we can get chamber
temperature as well as pressure. This
will mainly be useful at startup, but it may give us useful data during flight
if something goes wrong. I am going
with these amplifiers: http://www.axiomatic.com/thermo.html
To avoid having to build new cables for each engine, I am going to start
sharing power and ground between the pressure transducer, valve pot feedback,
and thermocouple. Considering the
magnitude of the noise we have at the PC104 system, I dont think this is going
to hurt us.
We have all the materials to put together a ship set of
engines with the new design, so we are shooting for another full vehicle warmup
test next weekend. If that works, we
will be aiming for a hover test the following week.
While driving home, I think I also put together another
piece of the puzzle. While scavenging
parts from some older engines, Matt noticed that there was a blued section
right in the middle of some of the screens above a monolith in one of the cold
packs. We always see some heat effected
areas around the outer edge of the screens, but we dont usually notice them in
the middle. I realized that there is
something in common between the center and the outer edge the top spreading
plate has the center blanked off and the holes are kept some extra distance
from the outer edge. This design makes
sense for a purely catalytic motor, because you want to avoid channeling around
the outer rim and taking too much of a high velocity hit right under the inlet,
but with our mixed catalytic / combustion engine, the areas with no propellant
feed (there are 10 screens between the spreading plate and the monolith, so it
spreads out some, but the edge and center are still going to get less) become
effectively internal flameholders. This
probably explains why the outside edge of the monoliths gets all pruned up
after running for a while the outer edges arent sitting at 100 C like the
rest of the catalyst, they have actual burning in them. These are probably also the local hot spots
that cause the startup problems. If we
eliminate these, we may not even need the initial slug of propellant to cool it
down. We arent going to change them
for this engine, but the next time I make spreading plates I am going to add an
explicit radial ring as close to the outside edge as we can get and still braze
the plate in place, and just run the grid all the way across the center without
a blanking spot. A little channeled
propellant doesnt hurt us, because it will just be burned in the hot pack. If that keeps the monoliths in better shape
and possibly avoids the hot start issue completely, it will be great.